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type="text/css"></style> <div id="ct" class="ct2 wp cl"> <div class="mn"> <div class="bm_haa cl"> <div class="bm_h cl"> <a href="http://www.oecr.com/portal.php?mod=rss&catid=57" class="y xi2 rss" target="_blank" title="RSS">订阅</a><h1 class="xs2">文章</h1> </div></div> <div class="kjkjb"> <div class="bm vw" style="margin-bottom:0;"> <div class="h hm"> <div class="zxtoux"><img src="http://www.oecr.com/uc_server/avatar.php?uid=54876&size=small" /></div> <h1 class="ph">安光所在时间分辨频率调制磁旋光谱探测技术方面取得新进展 </h1> <p class="xg1"> 时间：2023-7-28 09:13<a class="zz" href="home.php?mod=space&uid=54876">作者：update</a> 阅读<em id="_viewnum">(400)</em> 评论: <a href="http://www.oecr.com/portal.php?mod=comment&id=9827&idtype=aid" title="查看全部评论"><em id="_commentnum">5</em></a>来自: 安徽光机所</p> <div class="zxfb" ><a href="http://www.oecr.com/portal.php?mod=rss&catid=57" class="y xi2 rss" target="_blank" title="RSS">订阅</a></div> </div> <!--[diy=diysummarytop]--><div id="diysummarytop" class="area"></div><!--[/diy]--> <div class="s"> <div class="ss"><div><span>导读： </span>近日，中国科学院合肥物质院安光所张为俊研究员团队在时间分辨频率调制磁旋转光谱探测技术方面取得新进展，相关研究成果以《用于OH自由基时间分辨测量的高带宽中红外频率调制磁旋转光谱仪》为题发表于美国光学学会（ ...</div> </div> <!--[diy=diysummarybottom]--><div id="diysummarybottom" class="area"></div><!--[/diy]--> <div class="d"> <!--[diy=diycontenttop]--><div id="diycontenttop" class="area"></div><!--[/diy]--> <table cellpadding="0" cellspacing="0" class="vwtb"><tr><td id="article_content"><div> 近日，中国科学院合肥物质院安光所张为俊研究员团队在时间分辨频率调制磁旋转光谱探测技术方面取得新进展，相关研究成果以《用于OH自由基时间分辨<a href="http://opticaltest.oecr.com" target="_blank" class="relatedlink">测量</a>的高带宽中红外频率调制磁旋转光谱仪》为题发表于美国光学学会（OSA）出版的Optics Express上。</div><div><br></div><div> 羟基（OH）自由基是大气中最重要的氧化剂，启动了对流层大气中绝大部分的氧化反应。它浓度低、寿命短，实现高灵敏快速检测对于深入研究其化学反应动力学和机理、厘清大气污染成因具有极为重要的科学和应用意义。</div><div><br></div><div> 团队赵卫雄研究员和程飞虎博士等人发展的用于OH自由基高灵敏快速测量的频率调制磁旋转光谱技术具有高时间分辨、高灵敏度、选择性好的特点，特别适合短寿命自由基和中间体的动力学研究。实验中，针对266nm脉冲<a href="http://laser.oecr.com" target="_blank" class="relatedlink">激光</a>产生OH自由基，使用该技术测量了2.8微米附近的时间分辨光谱信号，经过3次脉冲平均，OH的检测线达到6.8×108分子/立方厘米(1σ,0.2 ms)，100次平均后，检测线可进一步下降到8.0×107分子/立方厘米。该技术不仅适用于OH自由基，也适用于其它顺磁性瞬态分子，将为自由基动力学研究提供一种新的重要测量手段。</div><div><br></div><div> 本研究得到国家自然科学基金、中国科学院青年创新促进会、中国科学院合肥物质科学研究院院长基金资助。</div><div><br></div><div> 文章链接：https://opg.optica.org/oe/fulltext.cfm?uri=oe-31-15-25058&id=532717</div><div><br></div><div><p style="text-align: center;"><a href="data/attachment/portal/202307/28/091601ix3bbxx3uycynyb3.png" target="_blank"><img src="data/attachment/portal/202307/28/091601ix3bbxx3uycynyb3.png"></a></p><p style="text-align: center;"><br></p><section microsoft="" yahei",="" simsun;="" margin:="" 0px;="" padding:="" background-color:="" rgb(255,="" 255,="" 255);"="" 255);="" overflow-wrap:="" normal;"="" style="word-wrap: normal; color: rgb(143, 143, 143); font-family: Tahoma, "Microsoft Yahei", Simsun; background-color: rgb(255, 255, 255);"><p style="word-wrap: normal; margin: 0px; padding: 0px 0px 1em; 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value="true" class="pn"><strong>评论</strong></button></p> </form> <a name="comment_anchor_33557"></a> <dl id="comment_33557_li" class="ptm pbm bbda cl"> <dt class="mbm"> <span class="y xw0 xi2"> <a href="javascript:;" onclick="portal_comment_requote(33557, '9827');">引用</a> </span> <a href="http://club.oecr.com/space-uid-4.html" class="xi2 xw1" c="1">angel</a> <span class="xg1 xw0">2023-7-28 10:43</span> </dt> <dd>说点什么呢？</dd> </dl><a name="comment_anchor_33556"></a> <dl id="comment_33556_li" class="ptm pbm bbda cl"> <dt class="mbm"> <span class="y xw0 xi2"> <a href="javascript:;" onclick="portal_comment_requote(33556, '9827');">引用</a> </span> <a href="http://club.oecr.com/space-uid-23351.html" class="xi2 xw1" c="1">flyersky</a> <span class="xg1 xw0">2023-7-28 10:13</span> </dt> <dd>谢谢分享这么好的内容。</dd> </dl><a name="comment_anchor_33555"></a> <dl id="comment_33555_li" class="ptm pbm bbda cl"> <dt class="mbm"> <span class="y xw0 xi2"> <a href="javascript:;" onclick="portal_comment_requote(33555, '9827');">引用</a> </span> <a href="http://club.oecr.com/space-uid-61367.html" class="xi2 xw1" c="1">jason2451</a> <span class="xg1 xw0">2023-7-28 09:43</span> </dt> <dd>我会推荐同事来这里的。</dd> </dl><a name="comment_anchor_33554"></a> <dl id="comment_33554_li" class="ptm pbm bbda cl"> <dt class="mbm"> <span class="y xw0 xi2"> <a href="javascript:;" onclick="portal_comment_requote(33554, '9827');">引用</a> </span> <a href="http://club.oecr.com/space-uid-97275.html" class="xi2 xw1" c="1">cxx1626</a> <span class="xg1 xw0">2023-7-28 09:13</span> </dt> <dd>…… 啥都不说了 很好</dd> </dl><a name="comment_anchor_33553"></a> <dl id="comment_33553_li" class="ptm pbm bbda cl"> <dt class="mbm"> <span class="y xw0 xi2"> <a href="javascript:;" onclick="portal_comment_requote(33553, '9827');">引用</a> </span> <a href="http://club.oecr.com/space-uid-64699.html" class="xi2 xw1" c="1">oxcn</a> <span class="xg1 xw0">2023-7-28 09:13</span> </dt> <dd>光电工程师社区是个好地方</dd> </dl></div> </div> 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