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type="text/css"></style> <div id="ct" class="ct2 wp cl"> <div class="mn"> <div class="bm_haa cl"> <div class="bm_h cl"> <a href="http://www.oecr.com/portal.php?mod=rss&catid=57" class="y xi2 rss" target="_blank" title="RSS">订阅</a><h1 class="xs2">文章</h1> </div></div> <div class="kjkjb"> <div class="bm vw" style="margin-bottom:0;"> <div class="h hm"> <div class="zxtoux"><img src="http://www.oecr.com/uc_server/avatar.php?uid=54876&size=small" /></div> <h1 class="ph">氟化硼酸盐深紫外非线性光学晶体研究取得进展 </h1> <p class="xg1"> 时间：2026-2-13 09:26<a class="zz" href="home.php?mod=space&uid=54876">作者：update</a> 阅读<em id="_viewnum">(15)</em> 评论: <a href="http://www.oecr.com/portal.php?mod=comment&id=10445&idtype=aid" title="查看全部评论"><em id="_commentnum">5</em></a></p> <div class="zxfb" ><a href="http://www.oecr.com/portal.php?mod=rss&catid=57" class="y xi2 rss" target="_blank" title="RSS">订阅</a></div> </div> <!--[diy=diysummarytop]--><div id="diysummarytop" class="area"></div><!--[/diy]--> <div class="s"> <div class="ss"><div><span>导读： </span>理想的深紫外非线性光学（NLO）晶体需同时具备大倍频响应、合适双折射和宽禁带等平衡光学特性。传统硼酸盐晶体（如β-BBO）大多难以实现直接深紫外倍频输出。目前实用的氟代硼铍酸钾（KBBF）晶体，存在层状生长习性 ...</div> </div> <!--[diy=diysummarybottom]--><div id="diysummarybottom" class="area"></div><!--[/diy]--> <div class="d"> <!--[diy=diycontenttop]--><div id="diycontenttop" class="area"></div><!--[/diy]--> <table cellpadding="0" cellspacing="0" class="vwtb"><tr><td id="article_content"><p style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; font-size: 16px; line-height: 1.5em; font-family: 微软雅黑; color: rgb(68, 68, 68); background-color: rgb(255, 255, 255); text-align: justify; text-indent: 2em; margin-bottom: 26px !important;"><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; text-indent: 0em; margin-bottom: 26px !important; line-height: 32px !important;">理想的深紫外</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">非线性光学（</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">NLO</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">）<a href="http://material.oecr.com" target="_blank" class="relatedlink">晶体</a></span>需同时具备大倍频响应、合适双折射和宽禁带等平衡光学特性<span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; text-indent: 0em; margin-bottom: 26px !important; line-height: 32px !important;">。传统硼酸盐晶体（如β-BBO）大多难以实现直接深紫外倍频输出。目前实用的氟代硼铍酸钾（KBBF）晶体，存在层状生长习性和原料毒性等缺陷。</span></p><p style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; font-size: 16px; line-height: 1.5em; font-family: 微软雅黑; color: rgb(68, 68, 68); background-color: rgb(255, 255, 255); text-align: justify; text-indent: 2em; margin-bottom: 26px !important;"><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">中国科学院新疆理化技术研究所研究团队提出，氟化多面体与平面</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">B-O</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">基团协同组装的结构设计策略。研究利用氟化多面体的</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">“</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">剪切</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">”</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">效应和定向聚合能力，实现</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">π</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">共轭功能单元的一致排列，成功合成系列碱金属氟化硼酸盐晶体</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">KABF</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">、</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">RABF</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">和</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">CABF</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">。</span></p><p style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; font-size: 16px; line-height: 1.5em; font-family: 微软雅黑; color: rgb(68, 68, 68); background-color: rgb(255, 255, 255); text-align: justify; text-indent: 2em; margin-bottom: 26px !important;"><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">该研究创新性在于通过氟化多面体调控平面</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">B-O</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">单元取向，构建出含</span><sup style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; line-height: 1.5em; margin-bottom: 26px !important; font-size: 16px !important;"><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">1</span></sup><sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; line-height: 1.5em; margin-bottom: 26px !important; font-size: 16px !important;"><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">∞</span></sub><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">[BO<sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; line-height: 1.5em; margin-bottom: 26px !important; font-size: 16px !important;">2</sub>]</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">链的新型结构，其中</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">[BO<sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; line-height: 1.5em; margin-bottom: 26px !important; font-size: 16px !important;">3</sub>F]<sup style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; line-height: 1.5em; margin-bottom: 26px !important; font-size: 16px !important;">4-</sup></span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">四面体与链状聚合</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">[BO<sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; line-height: 1.5em; margin-bottom: 26px !important; font-size: 16px !important;">3</sub>]<sup style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; line-height: 1.5em; margin-bottom: 26px !important; font-size: 16px !important;">3-</sup></span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">单元协同组装，形成平行排列的</span><sup style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; line-height: 1.5em; margin-bottom: 26px !important; font-size: 16px !important;"><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">2</span></sup><sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; line-height: 1.5em; margin-bottom: 26px !important; font-size: 16px !important;"><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">∞</span></sub><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">[B<sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; line-height: 1.5em; margin-bottom: 26px !important; font-size: 16px !important;">4</sub>O</span><sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; line-height: 1.5em; margin-bottom: 26px !important; font-size: 16px !important;"><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">6</span></sub><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">F]</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">层状结构。<a href="http://material.oecr.com" target="_blank" class="relatedlink">材料</a>表现出卓越性能：倍频响应达</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">1.6-1.7×KDP</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">（</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">1064nm</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">）和</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">0.4-0.5×BBO</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">（</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">532nm</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">），最短</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">I</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">类相位匹配波长低至</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">161.5<span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">nm至</span>168.6nm</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">，紫外截止边小于</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">190nm</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">。</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; text-indent: 0em; margin-bottom: 26px !important;">该策略突破了链状聚合</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; text-indent: 0em; margin-bottom: 26px !important;">[BO<sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; line-height: 1.5em; margin-bottom: 26px !important; font-size: 16px !important;">3</sub>]<sup style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; line-height: 1.5em; margin-bottom: 26px !important; font-size: 16px !important;">3-</sup></span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; text-indent: 0em; margin-bottom: 26px !important;">单元构建与非中心对称结构组装的控制难题，通过阳离子调控实现结构柔性适配，展现出氟化硼酸盐体系的结构稳定性与多样性。</span></p><p style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; font-size: 16px; line-height: 1.5em; font-family: 微软雅黑; color: rgb(68, 68, 68); background-color: rgb(255, 255, 255); text-align: justify; text-indent: 2em; margin-bottom: 26px !important;"><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">这项研究不仅为深紫外<span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">NLO</span>晶体提供了高性能候选材料，更确立了氟化多面体与聚合</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">BO<sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; line-height: 1.5em; margin-bottom: 26px !important; font-size: 16px !important;">3</sub></span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">单元协同作用的设计范式，为下一代无铍、低毒性深紫外<span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">NLO</span>材料的研发开辟了新路径。</span></p><p style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; font-size: 16px; line-height: 1.5em; font-family: 微软雅黑; color: rgb(68, 68, 68); background-color: rgb(255, 255, 255); text-align: justify; text-indent: 2em; margin-bottom: 26px !important;"><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;"></span></p><p style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; font-size: 16px; font-family: 微软雅黑; color: rgb(68, 68, 68); background-color: rgb(255, 255, 255); text-align: justify; text-indent: 2em; margin-bottom: 26px !important; line-height: 32px !important;"><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">相关研究成果以</span><em style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; line-height: 32px !important;">Constructing Deep-Ultraviolet Nonlinear Optical Crystals via Synergistic Combination of Fluorinated Polyhedra and Polymerized BO<sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; line-height: 1.5em; margin-bottom: 26px !important; font-size: 16px !important;">3</sub> Units</em><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">为题，发表在《先进功能材料》（</span><em style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; line-height: 32px !important;"><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">Advanced Functional Materials</span></em><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">）上。研究工作得到国家重点研发计划、新疆维吾尔自治区</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">“</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">天山英才</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">”</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">培养计划、中国科学院战略性先导科技专项等的支持。</span></p><p style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; font-size: 16px; font-family: 微软雅黑; color: rgb(68, 68, 68); background-color: rgb(255, 255, 255); text-indent: 2em; text-align: justify; margin-bottom: 26px !important; line-height: 32px !important;"><br></p><p style="text-align: center;"><a href="data/attachment/portal/202602/13/092533fiwi5owohkmzouij.png" target="_blank"><img src="data/attachment/portal/202602/13/092533fiwi5owohkmzouij.png"></a></p><p style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; font-size: 16px; font-family: 微软雅黑; color: rgb(68, 68, 68); background-color: rgb(255, 255, 255); text-align: center; margin-bottom: 26px !important; line-height: 32px !important;">氟化硼酸盐深紫外<span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; text-indent: 32px; margin-bottom: 26px !important; line-height: 32px !important;">NLO</span>晶体研究取得进展</p><p style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; font-size: 16px; font-family: 微软雅黑; color: rgb(68, 68, 68); background-color: rgb(255, 255, 255); text-align: center; margin-bottom: 26px !important; line-height: 32px !important;"><br></p><p style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; font-size: 16px; font-family: 微软雅黑; color: rgb(68, 68, 68); background-color: rgb(255, 255, 255); text-align: center; margin-bottom: 26px !important; line-height: 32px !important;"><br></p><p microsoft="" yahei",="" simsun;="" 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