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type="text/css"></style> <div id="ct" class="ct2 wp cl"> <div class="mn"> <div class="bm_haa cl"> <div class="bm_h cl"> <a href="http://www.oecr.com/portal.php?mod=rss&catid=58" class="y xi2 rss" target="_blank" title="RSS">订阅</a><h1 class="xs2">文章</h1> </div></div> <div class="kjkjb"> <div class="bm vw" style="margin-bottom:0;"> <div class="h hm"> <div class="zxtoux"><img src="http://www.oecr.com/uc_server/avatar.php?uid=54876&size=small" /></div> <h1 class="ph">X射线分析技术可提高碳捕获效率 </h1> <p class="xg1"> 时间：2012-8-20 09:28<a class="zz" href="home.php?mod=space&uid=54876">作者：update</a> 阅读<em id="_viewnum">(3822)</em> 评论: 0</p> <div class="zxfb" ><a href="http://www.oecr.com/portal.php?mod=rss&catid=58" class="y xi2 rss" target="_blank" title="RSS">订阅</a></div> </div> <!--[diy=diysummarytop]--><div id="diysummarytop" class="area"></div><!--[/diy]--> <div class="s"> <div class="ss"><div><span>导读： </span>最近，英国利兹大学工程系科学家利用同步加速器的钻石光源，从纳米尺度水平对氧化钙基的二氧化碳吸收剂进行了能效分析，解释了吸收过程中的关键机制，有望提高现有方法的效率，带来一种可大规模使用且经济高效的碳捕 ...</div> </div> <!--[diy=diysummarybottom]--><div id="diysummarybottom" class="area"></div><!--[/diy]--> <div class="d"> <!--[diy=diycontenttop]--><div id="diycontenttop" class="area"></div><!--[/diy]--> <table cellpadding="0" cellspacing="0" class="vwtb"><tr><td id="article_content"><P>最近，英国利兹大学工程系科学家利用同步加速器的钻石光源，从<a href="http://material.oecr.com" target="_blank" class="relatedlink">纳米</a>尺度水平对氧化钙基的二氧化碳吸收剂进行了能效分析，解释了吸收过程中的关键机制，有望提高现有方法的效率，带来一种可大规模使用且经济高效的碳捕获和存储方法。相关论文发表在最近出版的《能源与环境科学》杂志上。<BR> <BR>全球变暖引起人们越来越多的关注，各国都在想办法减少二氧化碳排放。发电厂烟囱里排出的气体中含有大量二氧化碳，要过滤这些二氧化碳实现碳捕获，现有吸收技术主要包括两种方法：一种是后燃烧，另一种是预燃烧。前者是在被加热之前，通过溶剂吸收二氧化碳放出水蒸气；后者是在化石燃料燃烧之前就通过催化剂接触转炉除去二氧化碳，由此燃烧后的二氧化碳就很少。这两种方法能将发电厂的碳排放减少80%—90%。<BR> <BR>氧化钙基吸收剂广泛用于这两种碳捕获技术中。它们量大成本低、吸收力强、反应迅速。温度范围在400℃—800℃时，它们能迅速捕获二氧化碳形成碳酸钙，以后还可以放出二氧化碳循环使用，二氧化碳可压缩存储。然而，经过多次碳捕获和再生循环后，由于烧结作用会使吸收剂表面积减少，粉末聚集成固体块，碳捕获能力就会下降。通过水合作用能恢复它们的表面积，但其<a href="http://machine.oecr.com" target="_blank" class="relatedlink">机械</a>强度会降低。如果能克服强度和表面积问题，氧化钙基吸收剂就能成为一种可大规模应用的低成本碳捕获剂。 </P> <P><A href="http://www.oecr.com/data/attachment/portal/201208/20/092808b5118vbjjkf5qkzf.jpg" target=_blank><IMG src="http://www.oecr.com/data/attachment/portal/201208/20/092808b5118vbjjkf5qkzf.jpg"></A></P> <P>为此，研究小组用钻石光源的高分辨率衍射光线进行了一系列实验，从纳米水平研究了氧化钙基<a href="http://material.oecr.com" target="_blank" class="relatedlink">材料</a>的碳捕获和水合过程。该项目博士生罗杰·莫林德说：“利用钻石同步加速器的高分辨率粉末衍射光束，我们能确定氢氧化物的形状和大小以及张力水平，得到这些衍生参数是理解烧结与瓦解机制的关键。传统光源会造成峰值重叠，无法做出这种分析。”<BR> <BR>研究人员发现，氧化钙遇到空气和水时，由于氧化物和氢氧化物的原子结构不同，容易形成一层氢氧化钙的外壳，接触面会产生很大的张力，使其破碎瓦解成纳米颗粒。该研究领导迪姆·柯明说：“由此我们也了解了蒸汽中的氧化钙捕获/瓦解能力为何会增强。下一步是开发出一种改进吸收剂的方法，把同样技术用于其他系统。”</P> <DIV><FONT color="#808080" size=2><IMG src="http://www.oecr.com/xwb/images/bgimg/icon_logo.png"> 已同步至 <a href="http://ome.ac.cn/index.php?m=show&id=3481036342461181" target="_blank">update的微博</A></FONT></DIV></td></tr></table> <!--[diy=diycontentbottom]--><div 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